Sodium ethanethiolate is an organosulfur compound with the formula CH3CH2SNa. It is the sodium salt of the conjugate base of ethanethiol. This compound is commercially available as a white solid that is soluble in polar organic solvents. Sodium ethanethiolate is a reagent in organic synthesis. Hydrolysis of sodium ethanethiolate, e.g. in humid air, produces ethanethiol, which has a low odor threshold and a noxious "rotten egg" smell. Preparation. Sodium ethanethiolate can be produced by treating a solution of ethanethiol with sodium hydride: The closely related sodium methanethiolate can be prepared and used in situ (i.e., without isolation) by treatment of a solution of methanethiol with strong base such as sodium hydroxide. Reactions. Sodium ethanethiolate is a source of ethanethiolate, a powerful nucleophile. It is used to cleave methoxy-aryl ethers: (Ar = aryl) It converts alkyl halides to ethyl thioethers (X = halogen, R = alkyl) Oxidation of sodium methanethiolate gives diethyldisulfide: